Stanford have an official how to install for dual gpu clients under Windows XP. This instructions is for the Nvidia console version.
Folding@home - WinGPUGuide
-Install the first video card and Nvidia CUDA drivers with at least the 177.35 version as per instruction above.
-Ensure that the card is stable and able to complete wu.
-Install the second video card and install the driver.
-Right click on any part of your windows desktop and left click on properties
-Click on settings tab and click on number two or second display (you would not see this if you only have one video card installed)
-Click/check on box
"Extend my windows desktop into this display". Click apply/ok and the second video card will be recognize by Windows XP. Vista is different and must have a dummy plug or actual monitor attached to video card before you can extend/recognize the second video card.
-On gpu0 folder run -configonly and change the additional client parameters to
-gpu 0 for the first video card. The system recognizes the first video card as -gpu 0
-On the second video card folder run -configonly and ensure that the client have a different machine id other than the default id of 2 which is more than likely the machine id for gpu 0. Machine id 3 is acceptable.
-The parameter
-gpu 1 must be added to again separate the first video card from the second. If you are lucky to have multiple video cards
-gpu 2 or the third,
gpu 3 are next.
-Create a shortcut for each client i.e. gpu60 and gpu61 and add to start up and monitor both gpu client until satisfied they are stable. Watch ppd increase in the next couple of days.
On my 8800GS I am able to OC the first video card using the EVGA Precision video card overclocking proggie. I use RivaTuner on my second video card as the overclocking proggie.