depending on what kind of a sight you want destructobro, i'd say. to be honest, i've tried both adobeGolive and Dreamweaver, and have to say that dreamweaver is way better. that's just my personal thought.
If you're versatile enough at html i found that my best sites are normally just hand coded in the netscape composer function of said browser. Having said that i do use dreamweaver a fair bit, simply because it's much tighter integrated with its' other relaeses, such as flash and fireworks and offers easier import facilities for given applications.
As far as wysiwyg (what-you-see-is-what-you-get) web applications go, i believe Dreamweaver to be the best solution to anyones webdesign needs.
steve.