The extra pins are to spread the load over more wires. If you check with a DMM, you'll find that all the same voltage pins (all the red pins, all the orange pins, etc.) in the ATX socket on the mobo are connected together within the mobo. You could treat the contacts within the connectors on the mobo and from the PSU with contact enhancer like Caig Labs ( http://www.caig.com ) Deoxit Gold (or Pro Gold as it was formerly named) to improve the current carrying capacity of the 20 wires. Caig products can be bought from McMaster-Carr ( www.mcmaster.com) or perhaps you can find it locally. I occasionally find it on eBay too. Great stuff for all your electrical gear, e.g. makes flashlight batteries last longer and the bulb burn brighter if you treat all the contact surfaces in there, etc.
.bh.
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