Further Info:
To boot from a SATA drive, you'll need to have the SATA drivers installed. In most cases..Windows would consider a SATA drive much like a SCSI device.
When you start a Win2000/XP install, simply press "F6" when booting from the CD. When prompted, pop in a floppy disk with the SATA controller drivers. (This lets Windows Setup talk to your drive.) The drivers can be found on the manufacturer of your motherboard (or add-in card if you are using a card.) If you do NOT press F6 and install the drivers, Windows setup will not even see that the drives exist.
Once the drivers are installed, you can boot to it without any problems. You may have to set your BIOS boot order to 'SCSI' to boot to the SATA drive.
If you need any more clarification, let us know!
- rp